SINTESIS 7-FORMILINDOL SEBAGAI BAHAN DASAR PEMBENTUK KATALIS EPOKSIDASI BARU

Authors

DOI:

https://doi.org/10.18269/jpmipa.v2i1.34901

Keywords:

Epoxidation catalyst,, indole, organometal catalyst

Abstract

Manganese (III) salen complexes have been reported as epoxidation catalysts. It is caused a major breakthrough in the enantioselective epoxidation of alkenes into epoxide compounds. This catalyst was synthesized from salicylaldehyde derivatives. Based on the structure, salicylaldehyde is an isosteric nature of 7-folmylindole, consequently opened the door to an array of fascinating and versatile ligand systems, and offer tremendous scope for molecular designe, because of the greatly enhanced capacity for substitution of indoles compared with phenols. Initial target of the project to synthesize of 7-formylindole. There are numerous strategies and methodes to achieve the target molecules. Further study of reaction mechanism of a useful target compound could be explanated and developed as a new class of catalyst. 

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Author Biography

  • H. Hayat Solihin, Indonesia University of Education

    Chemistry

References

Sholihin, H. and Black, D.StC., New Metal Complex Catalyst For Oxidation Reactions, PhD Thesis, UNSW, Australia, 1999.

Sheldon, R.A., and Kochi, J.K., Metal Catalysed Oxidation of Organic Compound, Academic Press, New York, 1981.

Jacobsen, E.N., Zhang, W., and Loebach, J.L., J. Am. Chem. Soc., 1990, 112, 2801-2803.

Jacobsen, E.N., Zhang, W., and Larrow, J.F.., J. Am. Chem. Soc., 1994, 116, 12129-12130.

Jacobsen, E.N., Catalytic Asymmetric Synthesis, 1993, Ed.I., Ojima, VCH, New York, 159-199.

Jacobsen, E.N., Zhang, W., and Brandes, B.D., Tetrahedron Lett., 1995, 36 (29), 51235126.

Groves, J.T., and Viski, P., J.Org. Chem., 1990, 55, 3628-3534.

Busch, D.H., J. Inclusion Phenomena and Molecular Recognition in Chemistry, 1992,12, 389-295.

Ungvary, F.J., J. Organometallic Chem., 1993, 457, 273-344.

Thomsen, D.S., Schiott, B., and Jorgensen, K.A., J. Chem. Soc., Chem. Commun., 1992, 1072-1074.

Morrison, D.J., Asymmetric Synthesis, Academic Press, N.Y., 1983

Mimoun, H., Comprehensive Coordination Chemistry, Pergamon Press, Oxford, vol 6, 1987.

Srinivasan, K., Michaud, P., and Kochi, J.K., J. Am. Chem. Soc., 1986, 108, 2309-2320

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Published

30-06-2001

How to Cite

SINTESIS 7-FORMILINDOL SEBAGAI BAHAN DASAR PEMBENTUK KATALIS EPOKSIDASI BARU. (2001). Jurnal Pengajaran Matematika Dan Ilmu Pengetahuan Alam, 2(1), 78-86. https://doi.org/10.18269/jpmipa.v2i1.34901